| Jornada 1 | 21/08/2011 | RAYO VALLEC. | 0 | MALLORCA | 1 |
| Jornada 2 | 28/08/2011 | ATHLETIC BILBAO | 1 | RAYO VALLEC. | 1 |
| Jornada 3 | 11/09/2011 | RAYO VALLEC. | 0 | ZARAGOZA | 0 |
| Jornada 4 | 18/09/2011 | GETAFE | 0 | RAYO VALLEC. | 1 |
| Jornada 5 | 21/09/2011 | RAYO VALLEC. | 1 | LEVANTE | 2 |
| Jornada 6 | 25/09/2011 | REAL MADRID | 6 | RAYO VALLEC. | 2 |
| Jornada 7 | 02/10/2011 | RAC.SANTANDER | 1 | RAYO VALLEC. | 1 |
| Jornada 8 | 16/10/2011 | RAYO VALLEC. | 0 | ESPANYOL | 1 |
| Jornada 9 | 23/10/2011 | BETIS | 0 | RAYO VALLEC. | 2 |
| Jornada 10 | 26/10/2011 | RAYO VALLEC. | 2 | MALAGA | 0 |
| Jornada 11 | 30/10/2011 | VILLARREAL | 2 | RAYO VALLEC. | 0 |
| Jornada 12 | 06/11/2011 | RAYO VALLEC. | 4 | REAL SOCIEDAD | 0 |
| Jornada 13 | 20/11/2011 | OSASUNA | 0 | RAYO VALLEC. | 0 |
| Jornada 14 | 27/11/2011 | RAYO VALLEC. | 1 | VALENCIA | 2 |
| Jornada 15 | 04/12/2011 | ATLETICO MADRID | 3 | RAYO VALLEC. | 1 |
| Jornada 16 | 11/12/2011 | RAYO VALLEC. | 1 | SPORTING GIJON | 3 |
| Jornada 17 | 18/12/2011 | FC BARCELONA | 4 | RAYO VALLEC. | 0 |
| Jornada 18 | 08/01/2012 | RAYO VALLEC. | 2 | SEVILLA | 1 |
| Jornada 19 | 15/01/2012 | GRANADA | 1 | RAYO VALLEC. | 2 |
| Jornada 20 | 22/01/2012 | MALLORCA | 1 | RAYO VALLEC. | 0 |
| Jornada 21 | 29/01/2012 | RAYO VALLEC. | 2 | ATHLETIC BILBAO | 3 |
| Jornada 22 | 05/02/2012 | ZARAGOZA | 1 | RAYO VALLEC. | 2 |
| Jornada 23 | 12/02/2012 | RAYO VALLEC. | 2 | GETAFE | 0 |
| Jornada 24 | 19/02/2012 | LEVANTE | 3 | RAYO VALLEC. | 5 |
| Jornada 25 | 26/02/2012 | RAYO VALLEC. | 0 | REAL MADRID | 1 |
| Jornada 26 | 04/03/2012 | RAYO VALLEC. | 4 | RAC.SANTANDER | 2 |
| Jornada 27 | 11/03/2012 | ESPANYOL | 5 | RAYO VALLEC. | 1 |
| Jornada 28 | 18/03/2012 | RAYO VALLEC. | 3 | BETIS | 0 |
| Jornada 29 | 21/03/2012 | MALAGA | 4 | RAYO VALLEC. | 2 |
| Jornada 30 | 25/03/2012 | RAYO VALLEC. | 0 | VILLARREAL | 2 |
| Jornada 31 | 01/04/2012 | REAL SOCIEDAD | 4 | RAYO VALLEC. | 0 |
| Jornada 32 | 08/04/2012 | RAYO VALLEC. | 6 | OSASUNA | 0 |
| Jornada 33 | 11/04/2012 | VALENCIA | 4 | RAYO VALLEC. | 1 |
| Jornada 34 | 15/04/2012 | RAYO VALLEC. | 0 | ATLETICO MADRID | 1 |
| Jornada 35 | 22/04/2012 | SPORTING GIJON | 2 | RAYO VALLEC. | 1 |
| Jornada 36 | 29/04/2012 | RAYO VALLEC. | 0 | FC BARCELONA | 7 |
| Jornada 37 | 06/05/2012 | SEVILLA | 5 | RAYO VALLEC. | 2 |
| Jornada 38 | 13/05/2012 | RAYO VALLEC. | 1 | GRANADA | 0 |